[180] Mechanochemical Protocol Facilitates the Generation of Arylmanganese Nucleophiles from Unactivated Manganese MetalTakahashi, R.; Gao, P.; Kubota, K.*; Ito, H.*
Chem. Rxiv.
2022,
DOI:
10.26434/chemrxiv-2022-48bnj
[179] Mechanical deformation and multiple thermal restoration of organic crystals: reversible multi-stage shape-changing effect with luminescence-color changesFeng, C.; Seki, T.*; Sakamoto, S.; Sasaki, T.; Takamizawa, S.*; Ito, H.*
Chem. Sci.
2022, Edge Article
DOI:
10.1039/D2SC03414J
[178] Stereospecific Synthesis of Silicon-Stereogenic Optically Active Silylboranes and their Application to Synthesis of Chiral OrganosilanesWang, X.; Feng, C.; Kubota, K.*; Ito, H.*
Chem. Rxiv.
2022,
DOI:
10.26434/chemrxiv-2022-ft3c6
[177] Cu(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl- and Silyl-substituted AlkenesOyama, N.; Akiyama, S.; Kubota, K.; Imamoto, T.; Ito, H.*
Eur. J. Org. Chem.
2022, e202200664.
DOI:
10.1002/ejoc.202200664
[176] Mechanochemically Generated Calcium-Based Heavy Grignard Reagents and Their Application to Carbon−Carbon Bond-Forming ReactionsGao, P.; Jiang, J.; Maeda, S.; Kubota, K.*; Ito, H.*
Angew. Chem. Int. Ed.
2022, Just Accepted
DOI:
10.1002/anie.202207118
[175] Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistryKubota, K.*; Baba, E.; Seo, T.; Ishiyama, T.; Ito, H.*
Beilstein J. Org. Chem.
2022,
18, 855.
DOI:
10.3762/bjoc.18.86
[174] Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditionsKubota, K.*; Seo, T.; Ito, H.*
Faraday Discuss.
2022, Just Accepted
DOI:
10.1039/D2FD00121G
[173] Conformationally Fixed Chiral Bisphosphine Ligands by Steric Modulators on the Ligand Backbone: Selective Synthesis of Strained 1,2-Disubstituted Chiral cis-CyclopropanesIwamoto, H.; Ozawa, Y.; Hayashi, Y.; Imamoto, T.; Ito, H.*
J. Am. Chem. Soc.
2022,
144, 10483 - 10494.
DOI:
10.1021/jacs.2c02745
[172] Insight into the Reactivity Profile of Solid-State Aryl Bromides in Suzuki-Miyaura Cross-Coupling Reactions Using Ball MillingKubota, K.*; Kondo, K.; Seo, T.; Ito, H.*
Synlett
2022,
33, 898 - 902.
DOI:
10.1055/a-1748-3797
[171] Distinct Fold-Mode Formation of Crystalline Cu(I) Helical Coordination Polymers with Alternation of the Solid-State Emission Using Shape of the Counter AnionsJin, M.*; Ando, R.; Ito, H.*
Inorg. Chem.
2022,
61, 3 - 9.
DOI:
https://doi.org/10.1021/acs.inorgchem.1c02725
[170] Efficient Access to Materials-Oriented Aromatic Alkynes via the Mechanochemical Sonogashira Coupling of Solid Aryl Halides with Large Polycyclic Conjugated SystemsGao, Y.; Feng, C.; Seo, T.; Kubota, K.*; Ito, H.*
Chem. Sci.
2022,
13, 430 - 438.
DOI:
10.1039/D1SC05257H
[169] Solid-State C−N Cross-Coupling Reactions with Carbazoles as Nitrogen Nucleophiles Using MechanochemistryKubota, K.*; Endo, T.; Uesugi, M.; Hayashi, Y.; Ito, H.*
ChemSusChem
2022,
15, e202102132.
DOI:
10.1002/cssc.202102132
[168] Palladium-Catalyzed Solid-State Polyfluoroarylation of Aryl Halides Using MechanochemistryTakahashi, R.; Seo, T.; Kubota, K.*; Ito, H.*
ACS Catal.
2021,
11, 14803 - 14810.
DOI:
10.1021/acscatal.1c03731
[167] Mechanochemical synthesis of magnesium-based carbon nucleophiles in air and their use in organic synthesisTakahashi, R.; Hu, A.; Gao, P.; Gao, Y.; Pang, Y.; Seo, T.; Maeda, S.; Jiang, J.; Takaya, H.; Kubota, K.*; Ito, H.*
Nature Commun.
2021,
12, 6691.
DOI:
10.1038/s41467-021-26962-w
[166] Single Crystal Growth of π-Conjugated Large Molecules without Solubilizing Alkyl Chains via Naphthalene Flux MethodYanase, T.; Tanoguchi, H.; Sakai, N.; Jin, M.; Yamane, I.; Kato, M.; Ito, H.; Nagahama, T.; Shimada, T.
Cryst. Growth. Des.
2021,
21, 4683 - 4689.
DOI:
https://doi.org/10.1021/acs.cgd.1c00538
[165] Regio- and Stereoselective Synthesis of Multi-Alkylated Allylic Boronates through Three-Component Coupling Reactions between Allenes, Alkyl Halides, and a Diboron ReagentOzawa, Y.; Endo, K.; Ito, H.*
J. Am. Chem. Soc.
2021,
143, 13865 - 13877.
DOI:
https://doi.org/10.1021/jacs.1c06538
[164] Synthesis of Hydrosilylboronates via the Monoborylation of a Dihydrosilane Si−H Bond and Their Application for the Generation of Dialkylhydrosilyl AnionsTakeuchi, T.; Shishido, R.; Kubota, K.*; Ito, H.*
Chem. Sci.
2021,
12, 11799 - 11804.
DOI:
10.1039/D1SC01440D
[163] Charge-Transfer Crystal with Segregated Packing Structure Constructed with Hexaarylbenzene and TetracyanoquinodimethaneAndo, R.; Jin, M.*; Ito, H.*
CrystEngComm
2021,
23, 5564 - 5568.
DOI:
10.1039/D1CE00726B
[162] Synthesis of Chiral α-Amino Tertiary Boronates via the Catalytic Enantioselective Nucleophilic Borylation of Dialkyl KetiminesKubota, K.*; Miura, D.; Takeuchi, T.; Osaki, S.; Ito, H.*
ACS Catal.
2021,
11, 6733 - 6740.
DOI:
10.1021/acscatal.1c01689
[161] Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent ReagentKubota, K.*; Toyoshima, N.; Miura, D.; Jiang, J.; Maeda, S.; Jin, M.*; Ito, H.*
Angew. Chem. Int. Ed.
2021,
60, 16003 - 16008.
DOI:
10.1002/anie.202105381
[160] Backbone-Modified C2-Symmetrical Chiral Bisphosphine TMS-QuinoxP*: Asymmetric Borylation of Racemic Allyl ElectrophilesIwamoto, H.; Ozawa, Y.; Takenouchi, Y.; Imamoto, T.; Ito, H.*
J. Am. Chem. Soc.
2021,
143, 6413 - 6422.
DOI:
10.1021/jacs.0c08899
[159] (9-Isocyanoanthracene)gold(I) Complexes Exhibiting Two Modes of Crystal Jumps by Different Structure Change MechanismsKato, K.; Seki, T.*; Ito, H.*
Inorg. Chem.
2021,
60, 10849 - 10856. Just Accepted
DOI:
10.1021/acs.inorgchem.1c00881
[158] Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl HalidesSeo, T.; Toyoshima, N; Kubota, K.*; Ito, H.*
J. Am. Chem. Soc.
2021,
143, 6165 - 6175.
DOI:
10.1021/jacs.1c00906
[157] A Copper(I)-Catalyzed Radical Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated OlefinsAkiyama, S.; Oyama, N.; Endo, T.; Kubota, K.; Ito, H.*
J. Am. Chem. Soc.
2021,
143, 5260 - 5268.
DOI:
10.1021/jacs.1c02050
[156] Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium AcyltrifluoroboratesMatsuura, S.; Taguchi, J.; Seki, T.; Ito, H.*
Bull. Chem. Soc. Jpn.
2021,
94, 1547 - 1552.
DOI:
10.1246/bcsj.20210024
[155] Encapsulating N-Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-StateJin, M.*; Ando, R.; Jellen, M. J.; Garcia-Garibay, M. A.; Ito, H.*
J. Am. Chem. Soc.
2021,
143, 1144 - 1153.
DOI:
https://doi.org/10.1021/jacs.0c11981
[154] Copper(I)-Catalyzed Stereoselective Silylative Dearomatization of Indoles and Pyrroles using SilylboronatesHayama, K.; Takahashi, Rikuro.; Kubota, K.; Ito, H.*
Chem. Lett.
2021,
50, 289 - 292.
DOI:
10.1246/cl.200725
[153] A Glove-box- and Schlenk-line-free Protocol for Solid-state C-N Cross-coupling Reactions Using MechanochemistryKubota, K.*; Takahashi, R.; Uesugi, M.; Ito, H.*
ACS Sustainable Chem. Eng.
2020,
8, 16577 - 16582.
DOI:
10.1021/acssuschemeng.0c05834
[152] Solid-State Radical C−H Trifluoromethylation Reactions Using Ball Milling and Piezoelectric MaterialsPang, Y.; Lee, J. W.; Kubota, K.*; Ito, H.*
Angew. Chem. Int. Ed.
2020,
59, 22570 - 22576.
DOI:
10.1002/anie.202009844 This is our second paper for mechanoredox reaction. See also,
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J. Am. Chem. Soc.
2020,
142, 14125 - 14133.
DOI:
10.1021/jacs.0c03011
[150] Selective Mechanochemical Monoarylation of Unbiased Dibromoarenes by In-situ CrystallizationSeo, T.; Kubota, K.*; Ito, H.*
J. Am. Chem. Soc.
2020,
142, 9884 - 9889.
DOI:
10.1021/jacs.0c01739 Under ball milling reaction conditions, palladium-catalyzed Suzuki–Miyaura cross-coupling reactions of unbiased dibromoarenes selectively afford the monoarylated products. This study gives a new approach that uses in-situ structure transitions in solids to achieve selective organic transformations difficult with traditional solution-based synthesis.
[149] Photoluminescent Ferroelastic Molecular CrystalsSeki, T.*; Feng, C.; Kashiyama, K.; Sakamoto, S.; Takasaki, Y.; Sasaki, T.; Takamizawa, S.*; Ito, H.*
Angew. Chem., Int. Ed.
2020,
59, 8839 - 8843.
DOI:
10.1002/anie.201914610 ・This is the first photoluminescent ferroelastic molecular crystals
・Crystals of arylgold(I)(N‐heterocyclic carbene)(NHC) complexes
・Mechanical‐stress‐induced shape change
[148] Copper(I)-Catalyzed Boryl Substitution of 1-Trifluoromethyl Allenes for the Synthesis of 3-Boryl-Substituted 1,1-gem-DifluorodienesAkiyama, S.; Nomura, S; Kubota, K.; Ito, H.*
J. Org. Chem.
2020,
85, 4172 - 4181.
DOI:
10.1021/acs.joc.9b03353 A method to synthesize 3-boryl-1,1-gem-difluorodienes via the copper(I)-catalyzed boryl substitution of trifluoromethyl-substituted allenes was developed. The borylated compounds were obtained up to 91% yield with excellent selectivity. We proposed that the reaction proceeded via γ-selective borylcupration into the trifluoromethyl-substituted allene, followed by copper(I)-β-fluoro elimination. Subsequent transformations of the borylation product by Suzuki–Miyaura cross-coupling or Diels–Alder reaction provided various compounds bearing a difluoro moiety, which are difficult to synthesize by existing methods.
[147] Mixed crystal formation of two gold isocyanide complexes with various ratios for continuous tuning of photophysical propertiesSeki, T.*; Toyoshima, N.; Ito, H.*
Dalton Trans.
2020,
49, 2073 - 2076.
DOI:
10.1039/D0DT00195C
[146] Silyl-group-directed Linear-selective Allylation of Carbonyl Compounds with Trisubstituted Allylboronates Using a Copper(I) CatalystIwamoto, H.; Hayashi, Y.; Ozawa, Y.; Ito, H.*
ACS Catal.
2020,
10, 2471 - 2476.
DOI:
10.1021/acscatal.9b05408
[145] Synthesis of Chiral N-Heterocyclic Allylboronates via the Enantioselective Borylative Dearomatization of PyrrolesHayama, K.; Kojima, R.; Kubota, K.; Ito, H.*
Org. Lett.
2020,
22, 739 - 744.
DOI:
10.1021/acs.orglett.9b04581
[144] Synthesis and Tunable Optical Properties of C,N-Chelated Borate Luminophores Derived from Potassium AcyltrifluoroboratesTaguchi, J.; Matsuura, S.; Seki, T.; Ito, H.*
Chem. Eur. J.
2020,
26, 2450 - 2455.
DOI:
10.1002/chem.201904983
[143] Crystal Jumping of Simple Hydrocarbons: Cooling-Induced Salient Effect of Bis-, Tri-, and Tetraphenylethene through Anisotropic Lattice Dimension Changes without Thermal Phase TransitionsSeki, T.*; Mashimo, T.; Ito, H.*
Chem. Lett.
2020,
49, 174 - 177.
DOI:
10.1246/cl.190768
[142] Aurophilicity-mediated Construction of Emissive Porous Molecular Crystals as Versatile Hosts for Liquid and Solid GuestsSeki, T.*; Ida, K.; Sato, H.; Aono, S.; Sakaki, S.; Ito, H.*
Chem. Eur. J.
2020,
26, 735 - 744.
DOI:
10.1002/chem.201904597
[141] Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactionsTakahashi, R.; Kubota, K.*; Ito, H.*
Chem. Commun.
2020,
56, 407 - 410.
DOI:
10.1039/C9CC06946A
[140] Redox Reactions of Small Organic Molecules Using Ball Milling and Piezoelectric MaterialsKubota, K.*; Pang, Y.; Miura, A.; Ito, H.*
Science
2019,
366, 1500 - 1504.
DOI:
10.1126/science.aay8224
[139] Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic CrystalsJin, M.; Yamamoto, S.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.*
Angew. Chem. Int. Ed.
2019,
58, 18003 - 18010.
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10.1002/anie.201909048
[138] The Direct Dimesitylborylation of Benzofuran Derivatives via an Iridium-Catalyzed C–H Activation with SilyldimesitylboraneShishido, R.; Sasaki, I.; Seki, T.; Ishiyama, T.; Ito, H.*
Chem. Eur. J.
2019,
25, 12924 - 12928.
DOI:
10.1002/chem.201903776
[137] Solid-State Suzuki-Miyaura Cross-Coupling Reactions: Olefin-Accelerated C–C Coupling Using MechanochemistrySeo, T.; Ishiyama, T.; Kubota, K.*; Ito, H.*
Chem. Sci.
2019,
10, 8202 - 8210.
DOI:
10.1039/C9SC02185J
[136] Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related DerivativesAkiyama, S.; Kubota, K.; Mikus, M. S.; Paioti, P. H. S.; Romiti, F.; Liu, Q.; Zhou, Y.; Hoveyda, A. H.*; Ito, H.*
Angew. Chem. Int. Ed.
2019,
58, 11998 - 12003.
DOI:
10.1002/anie.201906283 
Highlighted as a Frontispiece in Issue 35, 2019
[135] Copper(I)-Catalyzed Enantioconvergent Borylation of Racemic Benzyl Chlorides Enabled by Quadrant-by-Quadrant Structure Modulation of Chiral Bisphosphine LigandsIwamoto, H.; Endo, K.; Ozawa, Y.; Watanabe, Y.; Kubota, K.; Imamoto, T.; Ito, H.*
Angew. Chem. Int. Ed.
2019,
58, 11112 - 11117.
DOI:
10.1002/anie.201906011
[134] Synthesis of 2-alkyl-2-boryl-substituted-tetrahydrofurans via copper(I)-catalysed borylative cyclization of aliphatic ketonesKubota, K.; Uesugi, M.; Osaki, S.; Ito, H.*
Org. Biomol. Chem.
2019,
17, 5680 - 5683.
DOI:
10.1039/C9OB00962K
[133] Mechanochemistry allows carrying out sensitive organometallic reactions in air: Glove-box-and-Schlenk-line-free synthesis of oxidative addition complexes from aryl halides and palladium(0)Kubota, K.*; Takahashi, R.; Ito, H.*
Chem. Sci.
2019,
10, 5837 - 5842.
DOI:
10.1039/C9SC01711A
[132] Luminescent mechanochromism of gold N-heterocyclic carbene complexes with hypso- and bathochromic spectral shiftsSeki, T.*; Kashiyama, K.; Ito, H.*
Dalton Trans.
2019,
48, 7105 - 7109.
DOI:
10.1039/C9DT00566H
[131] Concise Synthesis of Potassium Acyltrifluoroborates from Aldehydes by a Cu(I)-catalyzed Borylation/Oxidation ProtocolTaguchi, J.; Takeuchi, T.; Takahashi, R.; Masero, F.; Ito, H.*
Angew. Chem. Int. Ed.
2019,
58, 7299 - 7303.
DOI:
10.1002/anie.201901748 
Highlighted as an insidecover in Issue 22, 2019
Top 10% downloaded paper 2018-2019[130] Anisotropic strain release in a thermosalient crystal: Correlation between the microscopic orientation of molecular rearrangements and the macroscopic mechanical motionSeki, T.*; Mashimo, T.; Ito, H.*
Chem. Sci.
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10, 4185 - 4191.
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10.1039/C8SC05563G
[129] Dependence of Absorption and Emission Spectra on Polymorphs of Gold(I) Isocyanide Complexes: Theoretical Study with QM/MM ApproachAono, S; Seki, T.; Ito, H.; Sakaki, S.*
J. Phys. Chem. C
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123, 4773 - 4794.
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10.1021/acs.jpcc.8b10602
[128] Iridium(I)-Catalyzed C-H Borylation in Air by Using MechanochemistryPang, Y.; Ishiyama, T.; Kubota, K.*; Ito, H.*
Chem. Eur. J.
2019,
25, 4654 - 4659.
DOI:
10.1002/chem.201900685
[127] Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistryKubota, K.*; Seo, T.; Koide, K.; Hasegawa, Y.; Ito, H.*
Nature Communications
2019,
10, 111.
DOI:
10.1038/s41467-018-08017-9 
https://www.nature.com/articles/s41467-018-08017-9
・北海道大学 PRESS RELEASE 固体状態で進行するクロスカップリング反応を開発
・Behind the Paper (Nature Research Chemistry Community) Cross-Coupling in Solid Using Mechanochemistry
・Highlighted in News Paper: 日経産業新聞20190111
・Highlighted in News Paper: 日刊工業新聞20190115
・Highlighted in News Web: NHK 北大 医薬品合成で新手法開発
・Highlighted in News Web: 環境展望台 北大 固体状態で進行する有機合成反応プロセスを開発
・Selected as "Nature Communications Editor's Highlights"
・Highlighted in Phys.org.: Boosting solid state chemical reactions
・Highlighted in Converter News: Olefin Enables Efficient Solvent-Free Cross-Coupling Reactions
・Highlighted in Technology Networks: Olefin Makes Chemistry Greener
・Highlighted in Chem Station: スポットライトリサーチ ”メカノケミストリーを用いた固体クロスカップリング反応"[126] Soft Crystal Force Field for Reproducing the Crystal Structures of Aryl Gold Isocyanide ComplexesNakayama, N.; Obata, S.; Hori, Y.; Goto, H.*; Seki, T.; Ito, H.
J. Comput. Chem. Jpn.
2018,
17, 155 - 157.
DOI:
10.2477/jccj.2018-0031
[125] A Gold Isocyanide Complex with a Pendant Carboxy Group: Orthogonal Molecular Arrangements and Hypsochromically Shifted Luminescent MechanochromismSeki, T.*; Kobayashi, K.; Mashimo, T.; Ito, H.*
Chem. Commun.
2018,
54, 13160 - 13160.
DOI:
10.1039/C8CC06490C
Correction: A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism
https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc90488j
[124] Copper(I)-Catalysed Stereoselective Debromoborylation of Aliphatic 1,1-Dibromo-1-Alkenes with Bis(pinacolato)diboronPang, Y.; Kojima, R.; Ito, H.*
Org. Biomol. Chem.
2018,
16, 6187 - 6190.
DOI:
10.1039/C8OB01778F
[123] Copper(I)-Catalyzed Stereoselective Defluoroborylation of Aliphatic Gem-DifluoroalkenesIto, H.*; Seo, T.; Kojima, R.; Kubota, K.
Chem. Lett.
2018,
47, 1330 - 1332.
DOI:
10.1246/cl.180656
[122] Computational design of high-performance ligand for enantioselective Markovnikov hydroboration of aliphatic terminal alkenesIwamoto, H.; Imamoto, T.; Ito, H.*
Nature Communications
2018,
9, 2290.
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10.1038/s41467-018-04693-9
[121] A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-substituted Alkenes: Synthesis of Enantioenriched γ,γ-gem-DifluoroallylboronatesKojima, R.; Akiyama, S.; Ito, H.*
Angew. Chem. Int. Ed.
2018,
57, 7196 - 7199.
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10.1002/anie.201803663
[120] Copper(I)-catalysed regio- and diastereoselective intramolecular alkylboration of terminal allenes via allylcopper(I) isomerizationOzawa, Y.; Iwamoto, H.; Ito, H.*
Chem. Commun.
2018,
54, 4991 - 4994.
DOI:
10.1039/C8CC02692K 
・Highlighted in Synfacts 2018, 14, 745. DOI: 10.1055/s-0037-1610101
[119] meta-diisocyanide benzene-based aryl gold isocyanide complex exhibiting multiple solid-state molecular arrangements and luminescent mechanochromismSeki, T.*; Ida, K.; Ito, H.*
Mater. Chem. Front.
2018,
2, 1195 - 1200.
DOI:
10.1039/C8QM00074C
[118] Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence ColorJin, M.; Sumitani, T.; Sato, H.; Seki, T.*; Ito, H.*
J. Am. Chem. Soc.
2018,
140, 2875 - 2879.
DOI:
10.1021/jacs.7b12455
[117] Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-bis[tri-(p-fluorophenyl)phosphane-gold(I)-ethynyl]benzeneJin, M.; Chung, T. J.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.*
J. Am. Chem. Soc.
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139, 18115 - 18121.
DOI:
10.1021/jacs.7b11316
[116] Copper(I)-Catalyzed Diastereoselective Dearomative Carboborylation of IndolesHayama, K.; Kubota, K.; Iwamoto, H.; Ito, H.*
Chem. Lett.
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46, 1800 - 1802.
DOI:
10.1246/cl.170825
[115] Copper(I)-Catalyzed Regio- and Stereoselective Intramolecular Alkylboration of Propargyl Ethers and AminesIwamoto, H.; Ozawa, Y.; Kubota, K.; Ito, H.*
J. Org. Chem.
2017,
82, 10563 - 10573.
DOI:
10.1021/acs.joc.7b02071
[114] Synthesis of Acylborons by Ozonolysis of Alkenylboronates: Preparation of an Enantioenriched Amino Acid AcylboronateTaguchi, J.; Ikeda, T.; Takahashi, R.; Sasaki, I.; Ogasawara, Y.; Dairi, T.; Kato, N.; Yamamoto, Y.; Bode, J. W.; Ito, H.*
Angew. Chem. Int. Ed.
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56, 13847 - 13851.
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10.1002/anie.201707933
[113] Stereodivergent Hydrodefluorination of gem-Difluoroalkenes: Selective Synthesis of (Z)- and (E)-MonofluoroalkenesKojima, R.; Kubota, K.; Ito, H.*
Chem. Commun.
2017,
53, 10688 - 10691.
DOI:
10.1039/C7CC05225A 
・Highlighted in Synfacts 2018, 14, 55. DOI: 10.1055/s-0036-1591076
[112] Tris(trimethylsilyl)silyl Boronate Esters: Novel Bulky, Air- and Moisture-Stable Silylboronate Ester Reagents for Boryl Substitution and Silaboration ReactionsYamamoto, E.; Shishido, R.; Seki, T.; Ito, H.*
Organometallics
2017,
36, 3019 - 3022.
DOI:
10.1021/acs.organomet.7b00476
[111] Formal Nucleophilic Silyl Substitution of Aryl Halides with Silyllithium Reagents via Halogenophilic Attack of Silyl NucleophilesYamamoto, E.; Ukigai, S.; Ito, H.*
Synlett
2017,
28, 2460 - 2464.
DOI:
10.1055/s-0036-1590835
[110] Tuning the Lifetime of Transient Phases of Mechanochromic Gold Isocyanide Complexes through Functionalization of the Terminal Moieties of Flexible Side ChainsSeki, T.*; Kashiyama, K.; Yagai, S.; Ito, H.*
Chem. Lett.
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46, 1415 - 1418.
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10.1246/cl.170482
[109] Triboluminescence of Lanthanide Coordination Polymers with Face-to-Face Arranged SubstituentsHirai, Y.; Nakanishi, T. ; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Hasegawa, Y.*
Angew. Chem. Int. Ed.
2017,
56, 7171 - 7175.
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10.1002/anie.201703638
[108] Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space GroupsJin, M.; Seki, T.*; Ito, H.*
J. Am. Chem. Soc.
2017,
139, 7452 - 7455.
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・プレスリリース: 簡便に発光ポリマーを調製する方法を開発
・Highlighted in Synfacts: Solid-State Suzuki-Miyaura Cross-Coupling of Insoluble Aryl Halides Using a Ball-Milling Approach
・プレスリリース: 溶けない化合物でも使えるクロスカップリング反応の開発
