瀬尾 珠恵 [Tamae Seo]



・錯体化学若手の会 北海道地区第8回勉強会 最優秀ポスター賞
・The 6.5th Crystal Engineering and Emerging Materials Workshop of Ontario and Quebec ACSYNAM Poster Prize
・Chem-Station スポットライトリサーチ 「不溶性アリールハライドの固体カップリング反応」

List of publication

[11] Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistry
Kubota, K.*; Baba, E.; Seo, T.; Ishiyama, T.; Ito, H.* Beilstein J. Org. Chem. 2022, 18, 855.
DOI: 10.3762/bjoc.18.86

[10] Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions
Kubota, K.*; Seo, T.; Ito, H.* Faraday Discuss. 2022, Just Accepted
DOI: 10.1039/D2FD00121G

[9] Insight into the Reactivity Profile of Solid-State Aryl Bromides in Suzuki-Miyaura Cross-Coupling Reactions Using Ball Milling
Kubota, K.*; Kondo, K.; Seo, T.; Ito, H.* Synlett 2022, 33, 898 - 902.
DOI: 10.1055/a-1748-3797

[8] Efficient Access to Materials-Oriented Aromatic Alkynes via the Mechanochemical Sonogashira Coupling of Solid Aryl Halides with Large Polycyclic Conjugated Systems
Gao, Y.; Feng, C.; Seo, T.; Kubota, K.*; Ito, H.* Chem. Sci. 2022, 13, 430 - 438.
DOI: 10.1039/D1SC05257H

[7] Palladium-Catalyzed Solid-State Polyfluoroarylation of Aryl Halides Using Mechanochemistry
Takahashi, R.; Seo, T.; Kubota, K.*; Ito, H.* ACS Catal. 2021, 11, 14803 - 14810.
DOI: 10.1021/acscatal.1c03731

[6] Mechanochemical synthesis of magnesium-based carbon nucleophiles in air and their use in organic synthesis
Takahashi, R.; Hu, A.; Gao, P.; Gao, Y.; Pang, Y.; Seo, T.; Maeda, S.; Jiang, J.; Takaya, H.; Kubota, K.*; Ito, H.* Nature Commun. 2021, 12, 6691.
DOI: 10.1038/s41467-021-26962-w

[5] Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides
Seo, T.; Toyoshima, N; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2021, 143, 6165 - 6175.
DOI: 10.1021/jacs.1c00906

[4] Selective Mechanochemical Monoarylation of Unbiased Dibromoarenes by In-situ Crystallization
Seo, T.; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2020, 142, 9884 - 9889.
DOI: 10.1021/jacs.0c01739
Under ball milling reaction conditions, palladium-catalyzed Suzuki–Miyaura cross-coupling reactions of unbiased dibromoarenes selectively afford the monoarylated products. This study gives a new approach that uses in-situ structure transitions in solids to achieve selective organic transformations difficult with traditional solution-based synthesis.

[3] Solid-State Suzuki-Miyaura Cross-Coupling Reactions: Olefin-Accelerated C–C Coupling Using Mechanochemistry
Seo, T.; Ishiyama, T.; Kubota, K.*; Ito, H.* Chem. Sci. 2019, 10, 8202 - 8210.
DOI: 10.1039/C9SC02185J

[2] Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry
Kubota, K.*; Seo, T.; Koide, K.; Hasegawa, Y.; Ito, H.* Nature Communications 2019, 10, 111.
DOI: 10.1038/s41467-018-08017-9
https://www.nature.com/articles/s41467-018-08017-9 ・北海道大学 PRESS RELEASE 固体状態で進行するクロスカップリング反応を開発 Behind the Paper (Nature Research Chemistry Community) Cross-Coupling in Solid Using MechanochemistryHighlighted in News Paper: 日経産業新聞20190111 ・Highlighted in News Paper: 日刊工業新聞20190115 ・Highlighted in News Web: NHK 北大 医薬品合成で新手法開発 Highlighted in News Web: 環境展望台 北大 固体状態で進行する有機合成反応プロセスを開発Selected as "Nature Communications Editor's Highlights"Highlighted in Phys.org.: Boosting solid state chemical reactionsHighlighted in Converter News: Olefin Enables Efficient Solvent-Free Cross-Coupling ReactionsHighlighted in Technology Networks: Olefin Makes Chemistry GreenerHighlighted in Chem Station: スポットライトリサーチ ”メカノケミストリーを用いた固体クロスカップリング反応"

[1] Copper(I)-Catalyzed Stereoselective Defluoroborylation of Aliphatic Gem-Difluoroalkenes
Ito, H.*; Seo, T.; Kojima, R.; Kubota, K. Chem. Lett. 2018, 47, 1330 - 1332.
DOI: 10.1246/cl.180656