PUBLICATIONS

Mechanochemical Generation of Aryl Barium Nucleophiles from Unactivated Barium Metal

Kubota, K.*; Kawamura, S.; Jiang, J.; Maeda, S.; Ito, H.* Chem. Sci. 2024, Just Accepted
DOI: 10.1039/D4SC05361C

Direct arylation of alkyl fluorides using in situ mechanochemically generated calcium-based heavy Grignard reagents

Gao, P.; Jiang, J.; Fukuzawa, Y.; Maeda, S.; Kubota, K.*; Ito, H.* RSC Mechanochem. 2024, 1, 486–491.
DOI: 10.1039/D4MR00067F

Solid-state Dynamics of Binuclear N-Heterocyclic Carbene Au(I) Rotor with para-Phenylene Rotator

Jiang, P.; Mikherdov, A. S.; Ito, H.*; Jin, M.* Chem. Lett. 2024, upae139.
DOI: doi.org/10.1093/chemle/upae139

Dissolution-Limited Reactions in Solid-State Synthesis

Yamamoto, T.*; Kubota, K.; Ito, H. J. Soc. Rheol. Jpn. 2024, 52, 161–170.
DOI: 10.1678/rheology.52.161

Crystallization-Induced Chirality Transfer in Conformationally Flexible Azahelicene Au(I) Complexes with Circularly Polarized Luminescence Activation

Jiang, P.; Mikherdov, A. S. ; Ito, H.*; Jin, M.* J. Am. Chem. Soc. 2024, 146, 12463–12472.
DOI: 10.1021/jacs.4c00345

Mechanochemistry Enabled Highly Efficient Solvent-Free Deoxygenation of Phosphine Oxides in Air

Kubota, K.*; Hisazumi, R.; Seo, T.; Ito, H.* RSC Mechanochem. 2024, 1, 250–254.
DOI: 10.1039/D4MR00011K

Highly Efficient and Air-tolerant Calcium-based Birch Reduction Using Mechanochemistry

Kubota, K.*; Fukuzawa, Y.; Kondo, K.; Gao, Y.; Ito, H.* Chem. Lett. 2024, 53, upae060.
DOI: 10.1093/chemle/upae060

Solid-state nickel(0)-mediated Yamamoto coupling enabled by mechanochemistry

Kubota, K.*; Shizukuishi, N.; Kubo, S.; Ito, H.* Chem. Lett. 2024, 53, upae056.
DOI: 10.1093/chemle/upae056

Mechanochemistry enabling highly efficient Birch reduction using sodium lumps and D-(+)-glucose

Kondo, K.; Kubota, K.*; Ito, H.* Chem. Sci. 2024, 15, 4452–4457.
DOI: 10.1039/D3SC06052G

Solid-State Mechanochemistry for the Rapid and Efficient Synthesis of Tris-Cyclometalated Iridium(III) Complexes

Kubota, K.*; Endo, T.; Ito, H.* Chem. Sci. 2024, 15, 3365–3371.
DOI: 10.1039/D3SC05796H

Ring Expansion of Cyclic Boronates via Oxyboration of Arynes

Shiratori, Y. ; Jiang, J.; Kubota, K.; Maeda, S; Ito, H.* J. Am. Chem. Soc. 2024, 146, 1765.
DOI: 10.1021/jacs.3c11851

Using Mechanochemistry to Activate Commodity Plastics as Initiators for Radical Chain Reactions of Small Organic Molecules

Kubota, K.*; Jiang, J.; Kamakura, Y.; Hisazumi, R.; Endo, T.; Miura, D.; Kubo, S.; Maeda, S.; Ito, H.* J. Am. Chem. Soc. 2024, 146, 1062.
DOI: 10.1021/jacs.3c12049

A Steric-Repulsion-Driven Clutch Stack of Triaryltriazines: Correlated Molecular Rotations and a Thermo-Responsive Gear-shift in the Crystalline Solid

Jin, M.*; Kitsu, R.; Hammyo, N.; Sato-Tomita, A.; Mizuno, M.; Mikherdov, A. S.; Tsitsvero, M.; Lyalin, A.; Taketsugu, T.; Ito, H.* J. Am. Chem. Soc. 2023, 145, 27512.
DOI: 10.1021/jacs.3c08909

Mechanochemical Synthesis of Non-Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species

Kurumada, S.; Yamanashi, R.; Sugita, K.; Kubota, K.; Ito, H.; Ikemoto, S.; Chen, C.; Moriyama, T.; Muratsugu, S.; Tada, M.; Koitaya, T.; Ozaki, T.; Yamashita, M.* Chem. Eur. J. 2023, e202303073.
DOI: 10.1002/chem.202303073

Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: Uniform synthesis of nonsubstituted linear oligothiophenes

Kubota, K.*; Kondo, K.; Seo, T.; Jin, M.; Ito, H.* RSC Adv. 2023, 13, 28652–28657.
DOI: 10.1039/D3RA05571J

Stereospecific synthesis of silicon-stereogenic optically active silylboranes and general synthesis of chiral silyl anions

Wang, X.; Feng, C.; Jiang, J.; Maeda, S.; Kubota, K.*; Ito, H.* Nature Commun. 2023, 14, 5561.
DOI: 10.1038/s41467-023-41113-z

Giant Crystalline Molecular Rotors that Operate in the Solid State

Ando, R.; Sato-Tomita, A.; Ito, H.*; Jin, M.* Angew. Chem. Int. Ed. 2023, 135, e202309694.
DOI: 10.1002/ange.202309694

Dual Nickel(II)/Mechanoredox Catalysis: Mechanical-force-driven Aryl-amination Reactions Using Ball Milling and Piezoelectric Materials

Seo, T.; Kubota, K.*; Ito, H.* Angew. Chem. Int. Ed. 2023, 62, e202311531.
DOI: 10.1002/anie.202311531

Synthesis of (Z)-alkenyl boronates via a copper(I)-catalyzed linear-selective alkylboration of terminal allenes

Ozawa, Y.; Shiratori, Y.; Koriyama, H.; Endo, K.; Iwamoto, H.; Ito, H.* Org. Chem. Front. 2023, 10, 4786–4793.
DOI: 10.1039/D3QO01095C

Synthesis of Fluoromethyl-substituted Cyclopropanes by Electrophilic Cyclization of Homoallylic Boronate Intermediates

Oyama, N.; Ito, H.* Adv. Synth. Catal. 2023, 365, 3241–3246.
DOI: 10.1002/adsc.202300529

Iterative Synthesis of Oligosilanes Using Methoxyphenyl- or Hydrogen-Substituted Silylboronates as Building Blocks: A General Synthetic Method for Complex Oligosilanes

Takeuchi, T.; Roy, A.; Ito, H.* J. Am. Chem. Soc. 2023, 145, 16249–16260.
DOI: doi.org/10.1021/jacs.3c05385

Construction of a Helical Structure with a Parallel Alignment of Molecular Dipoles in Crystals by Utilizing a Halogen-3 Synthon and a Bulky Silyl Spacer

Hammyo, N.; Jin, M.*; Ito, H.* Cryst. Growth Des. 2023, 23, 4514–4521.
DOI: 10.1021/acs.cgd.3c00282

Exploring Au(I) Involving Halogen Bonding with N-Heterocyclic Carbene Au(I) Aryl Complexes in Crystalline Media

Mikherdov, A. S.; Jin, M.*; Ito, H.* Chem. Sci. 2023, 14, 4485–4494.
DOI: 10.1039/D3SC00373F

An Improved Catalytic System for Solid-state Iridium(I)-catalyzed C–H Borylation Using Mechanochemistry

Kondo, K.; Kubota, K.*; Ito, H.* Chem. Lett. 2023, 52, 333–336.
DOI: 10.1246/cl.230081

Mechanochemical Approach for Air-Tolerant and Extremely Fast Lithium-Based Birch Reductions in Minutes

Gao, Y.; Kubota, K.*; Ito, H.* Angew. Chem. Int. Ed. 2023, 62, e202217723.
DOI: 10.1002/anie.202217723

In Situ and Real-Time Visualization of Mechanochemical Damage in Double-Network Hydrogels by Prefluorescent Probe via Oxygen-Relayed Radical Trapping

Zheng, Y.; Jiang, J.; Jin, M.*; Miura, D.; Lu, F. X.; Kubota, K.; Nakajima, T.; Maeda, S.*; Ito, H.*; Gong, J. P.* J. Am. Chem. Soc. 2023, 145, 7376–7389.
DOI: 10.1021/jacs.2c13764

Mechanochemistry-Directed Ligand Design: Development of a High-Performance Phosphine Ligand for Palladium-Catalyzed Mechanochemical Organoboron Cross-Coupling

Seo, T.; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2023, 145, 6823–6837.
DOI: 10.1021/jacs.2c13543

Multidynamic Crystalline Molecular Rotors Comprising an N-Heterocyclic Carbene Binuclear Au(I) Complex Bearing Multiple Rotators

Jin, M.*; Matsuura, S.; Yamamoto, H.; Mizuno, M.; Ito, H.* Eur. J. Org. Chem. 2023, 26, e202201468.
DOI: 10.1002/ejoc.202201468

Solid-state Silver-catalyzed Ring-opening Fluorination of Cyclobutanols Using Mechanochemistry

Isshiki, R.*; Kubota, K.*; Ito, H.* Synlett 2023, 34, 1419–1424.
DOI: 10.1055/a-2021-9599

Copper(I)-Catalyzed Regio- and Stereoselective Silaboration of Terminal Allenes

Ozawa, Y.; Koriyama, H.; Shiratori, Y.; Ito, H.* ACS Org. Inorg. Au 2023, 3, 104–108.
DOI: 10.1021/acsorginorgau.2c00057

Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions

Kubota, K.*; Seo, T.; Ito, H.* Faraday Discuss. 2023, 241, 104–113.
DOI: 10.1039/D2FD00121G

Mechanochemical Protocol Facilitates the Generation of Arylmanganese Nucleophiles from Unactivated Manganese Metal

Takahashi, R.; Gao, P.; Kubota, K.*; Ito, H.* Chem. Sci. 2023, 14, 499–505.
DOI: 10.1039/D2SC05468J

Mechanical deformation and multiple thermal restoration of organic crystals: reversible multi-stage shape-changing effect with luminescence-color changes

Feng, C.; Seki, T.*; Sakamoto, S.; Sasaki, T.; Takamizawa, S.*; Ito, H.* Chem. Sci. 2022, 13, 9544–9551.
DOI: 10.1039/D2SC03414J

Cu(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl- and Silyl-substituted Alkenes

Oyama, N.; Akiyama, S.; Kubota, K.; Imamoto, T.; Ito, H.* Eur. J. Org. Chem. 2022, e202200664.
DOI: 10.1002/ejoc.202200664

Mechanochemically Generated Calcium-Based Heavy Grignard Reagents and Their Application to Carbon−Carbon Bond-Forming Reactions

Gao, P.; Jiang, J.; Maeda, S.; Kubota, K.*; Ito, H.* Angew. Chem. Int. Ed. 2022, 61, e202207118.
DOI: 10.1002/anie.202207118

Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistry

Kubota, K.*; Baba, E.; Seo, T.; Ishiyama, T.; Ito, H.* Beilstein J. Org. Chem. 2022, 18, 855.
DOI: 10.3762/bjoc.18.86

Conformationally Fixed Chiral Bisphosphine Ligands by Steric Modulators on the Ligand Backbone: Selective Synthesis of Strained 1,2-Disubstituted Chiral cis-Cyclopropanes

Iwamoto, H.; Ozawa, Y.; Hayashi, Y.; Imamoto, T.; Ito, H.* J. Am. Chem. Soc. 2022, 144, 10483–10494.
DOI: 10.1021/jacs.2c02745

Insight into the Reactivity Profile of Solid-State Aryl Bromides in Suzuki-Miyaura Cross-Coupling Reactions Using Ball Milling

Kubota, K.*; Kondo, K.; Seo, T.; Ito, H.* Synlett 2022, 33, 898–902.
DOI: 10.1055/a-1748-3797

Distinct Fold-Mode Formation of Crystalline Cu(I) Helical Coordination Polymers with Alternation of the Solid-State Emission Using Shape of the Counter Anions

Jin, M.*; Ando, R.; Ito, H.* Inorg. Chem. 2022, 61, 3–9.
DOI: https://doi.org/10.1021/acs.inorgchem.1c02725

Efficient Access to Materials-Oriented Aromatic Alkynes via the Mechanochemical Sonogashira Coupling of Solid Aryl Halides with Large Polycyclic Conjugated Systems

Gao, Y.; Feng, C.; Seo, T.; Kubota, K.*; Ito, H.* Chem. Sci. 2022, 13, 430–438.
DOI: 10.1039/D1SC05257H

Solid-State C−N Cross-Coupling Reactions with Carbazoles as Nitrogen Nucleophiles Using Mechanochemistry

Kubota, K.*; Endo, T.; Uesugi, M.; Hayashi, Y.; Ito, H.* ChemSusChem 2022, 15, e202102132.
DOI: 10.1002/cssc.202102132

Development of Selective Reactions Using Ball Milling

Kubota, K.*; Ito, H.* J. Synth. Org. Chem. Jpn. 2021, 79, 492–502.
DOI: 10.5059/yukigoseikyokaishi.79.492

Palladium-Catalyzed Solid-State Polyfluoroarylation of Aryl Halides Using Mechanochemistry

Takahashi, Rikuro; Seo, T.; Kubota, K.*; Ito, H.* ACS Catal. 2021, 11, 14803–14810.
DOI: 10.1021/acscatal.1c03731

Mechanochemical synthesis of magnesium-based carbon nucleophiles in air and their use in organic synthesis

Takahashi, R.; Hu, A.; Gao, P.; Gao, Y.; Pang, Y.; Seo, T.; Maeda, S.; Jiang, J.; Takaya, H.; Kubota, K.*; Ito, H.* Nature Commun. 2021, 12, 6691.
DOI: 10.1038/s41467-021-26962-w

Single Crystal Growth of π-Conjugated Large Molecules without Solubilizing Alkyl Chains via Naphthalene Flux Method

Yanase, T.; Tanoguchi, H.; Sakai, N.; Jin, M.; Yamane, I.; Kato, M.; Ito, H.; Nagahama, T.; Shimada, T. Cryst. Growth. Des. 2021, 21, 4683–4689.
DOI: https://doi.org/10.1021/acs.cgd.1c00538

Regio- and Stereoselective Synthesis of Multi-Alkylated Allylic Boronates through Three-Component Coupling Reactions between Allenes, Alkyl Halides, and a Diboron Reagent

Ozawa, Y.; Endo, K.; Ito, H.* J. Am. Chem. Soc. 2021, 143, 13865–13877.
DOI: https://doi.org/10.1021/jacs.1c06538

Synthesis of Hydrosilylboronates via the Monoborylation of a Dihydrosilane Si−H Bond and Their Application for the Generation of Dialkylhydrosilyl Anions

Takeuchi, T.; Shishido, R.; Kubota, K.*; Ito, H.* Chem. Sci. 2021, 12, 11799–11804.
DOI: 10.1039/D1SC01440D

Charge-Transfer Crystal with Segregated Packing Structure Constructed with Hexaarylbenzene and Tetracyanoquinodimethane

Ando, R.; Jin, M.*; Ito, H.* CrystEngComm 2021, 23, 5564–5568.
DOI: 10.1039/D1CE00726B

Synthesis of Chiral α-Amino Tertiary Boronates via the Catalytic Enantioselective Nucleophilic Borylation of Dialkyl Ketimines

Kubota, K.*; Miura, D.; Takeuchi, T.; Osaki, S.; Ito, H.* ACS Catal. 2021, 11, 6733–6740.
DOI: 10.1021/acscatal.1c01689

Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent Reagent

Kubota, K.*; Toyoshima, N.; Miura, D.; Jiang, J.; Maeda, S.; Jin, M.*; Ito, H.* Angew. Chem. Int. Ed. 2021, 60, 16003–16008.
DOI: 10.1002/anie.202105381

Backbone-Modified C2-Symmetrical Chiral Bisphosphine TMS-QuinoxP*: Asymmetric Borylation of Racemic Allyl Electrophiles

Iwamoto, H.; Ozawa, Y.; Takenouchi, Y.; Imamoto, T.; Ito, H.* J. Am. Chem. Soc. 2021, 143, 6413–6422.
DOI: 10.1021/jacs.0c08899

(9-Isocyanoanthracene)gold(I) Complexes Exhibiting Two Modes of Crystal Jumps by Different Structure Change Mechanisms

Kato, K.; Seki, T.*; Ito, H.* Inorg. Chem. 2021, 60, 10849–10856. Just Accepted
DOI: 10.1021/acs.inorgchem.1c00881

Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides

Seo, T.; Toyoshima, N; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2021, 143, 6165–6175.
DOI: 10.1021/jacs.1c00906

A Copper(I)-Catalyzed Radical Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated Olefins

Akiyama, S.; Oyama, N.; Endo, T.; Kubota, K.; Ito, H.* J. Am. Chem. Soc. 2021, 143, 5260–5268.
DOI: 10.1021/jacs.1c02050

Synthesis and Optical Properties of C,N-Swapped Boranils Derived from Potassium Acyltrifluoroborates

Matsuura, S.; Taguchi, J.; Seki, T.; Ito, H.* Bull. Chem. Soc. Jpn. 2021, 94, 1547–1552.
DOI: 10.1246/bcsj.20210024

Encapsulating N-Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State

Jin, M.*; Ando, R.; Jellen, M. J.; Garcia-Garibay, M. A.; Ito, H.* J. Am. Chem. Soc. 2021, 143, 1144–1153.
DOI: https://doi.org/10.1021/jacs.0c11981

Copper(I)-Catalyzed Stereoselective Silylative Dearomatization of Indoles and Pyrroles using Silylboronates

Hayama, K.; Takahashi, Rikuro.; Kubota, K.; Ito, H.* Chem. Lett. 2021, 50, 289–292.
DOI: 10.1246/cl.200725

A Glove-box- and Schlenk-line-free Protocol for Solid-state C-N Cross-coupling Reactions Using Mechanochemistry

Kubota, K.*; Takahashi, Rikuro; Uesugi, M.; Ito, H.* ACS Sustainable Chem. Eng. 2020, 8, 16577–16582.
DOI: 10.1021/acssuschemeng.0c05834

Solid-State Radical C−H Trifluoromethylation Reactions Using Ball Milling and Piezoelectric Materials

Pang, Y.; Lee, J. W.; Kubota, K.*; Ito, H.* Angew. Chem. Int. Ed. 2020, 59, 22570–22576.
DOI: 10.1002/anie.202009844

General Synthesis of Trialkyl- and Dialkylarylsilylboranes: Versatile Silicon Nucleophiles in Organic Synthesis

Shishido, R.; Uesugi, M.; Takahashi, Rikuro.; Mita, T.; Ishiyama, T.; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2020, 142, 14125–14133.
DOI: 10.1021/jacs.0c03011

Selective Mechanochemical Monoarylation of Unbiased Dibromoarenes by In-situ Crystallization

Seo, T.; Kubota, K.*; Ito, H.* J. Am. Chem. Soc. 2020, 142, 9884–9889.
DOI: 10.1021/jacs.0c01739

Photoluminescent Ferroelastic Molecular Crystals

Seki, T.*; Feng, C.; Kashiyama, K.; Sakamoto, S.; Takasaki, Y.; Sasaki, T.; Takamizawa, S.*; Ito, H.* Angew. Chem., Int. Ed. 2020, 59, 8839–8843.
DOI: 10.1002/anie.201914610

Copper(I)-Catalyzed Boryl Substitution of 1-Trifluoromethyl Allenes for the Synthesis of 3-Boryl-Substituted 1,1-gem-Difluorodienes

Akiyama, S.; Nomura, S; Kubota, K.; Ito, H.* J. Org. Chem. 2020, 85, 4172–4181.
DOI: 10.1021/acs.joc.9b03353

Mixed crystal formation of two gold isocyanide complexes with various ratios for continuous tuning of photophysical properties

Seki, T.*; Toyoshima, N.; Ito, H.* Dalton Trans. 2020, 49, 2073–2076.
DOI: 10.1039/D0DT00195C

Silyl-group-directed Linear-selective Allylation of Carbonyl Compounds with Trisubstituted Allylboronates Using a Copper(I) Catalyst

Iwamoto, H.; Hayashi, Y.; Ozawa, Y.; Ito, H.* ACS Catal. 2020, 10, 2471–2476.
DOI: 10.1021/acscatal.9b05408

Synthesis of Chiral N-Heterocyclic Allylboronates via the Enantioselective Borylative Dearomatization of Pyrroles

Hayama, K.; Kojima, R.; Kubota, K.; Ito, H.* Org. Lett. 2020, 22, 739–744.
DOI: 10.1021/acs.orglett.9b04581

Synthesis and Tunable Optical Properties of C,N-Chelated Borate Luminophores Derived from Potassium Acyltrifluoroborates

Taguchi, J.; Matsuura, S.; Seki, T.; Ito, H.* Chem. Eur. J. 2020, 26, 2450–2455.
DOI: 10.1002/chem.201904983

Crystal Jumping of Simple Hydrocarbons: Cooling-Induced Salient Effect of Bis-, Tri-, and Tetraphenylethene through Anisotropic Lattice Dimension Changes without Thermal Phase Transitions

Seki, T.*; Mashimo, T.; Ito, H.* Chem. Lett. 2020, 49, 174–177.
DOI: 10.1246/cl.190768

Aurophilicity-mediated Construction of Emissive Porous Molecular Crystals as Versatile Hosts for Liquid and Solid Guests

Seki, T.*; Ida, K.; Sato, H.; Aono, S.; Sakaki, S.; Ito, H.* Chem. Eur. J. 2020, 26, 735–744.
DOI: 10.1002/chem.201904597

Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions

Takahashi, R.; Kubota, K.*; Ito, H.* Chem. Commun. 2020, 56, 407–410.
DOI: 10.1039/C9CC06946A

Mechanochemical cross-coupling reactions

Kubota, K.*; Ito, H.* Trends Chem. 2020, 2, 1066–1081.
DOI: 10.1016/j.trechm.2020.09.006

Redox Reactions of Small Organic Molecules Using Ball Milling and Piezoelectric Materials

Kubota, K.*; Pang, Y.; Miura, A.; Ito, H.* Science 2019, 366, 1500–1504.
DOI: 10.1126/science.aay8224

Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals

Jin, M.; Yamamoto, S.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.* Angew. Chem. Int. Ed. 2019, 58, 18003–18010.
DOI: 10.1002/anie.201909048

The Direct Dimesitylborylation of Benzofuran Derivatives via an Iridium-Catalyzed C–H Activation with Silyldimesitylborane

Shishido, R.; Sasaki, I.; Seki, T.; Ishiyama, T.; Ito, H.* Chem. Eur. J. 2019, 25, 12924–12928.
DOI: 10.1002/chem.201903776

Solid-State Suzuki-Miyaura Cross-Coupling Reactions: Olefin-Accelerated C–C Coupling Using Mechanochemistry

Seo, T.; Ishiyama, T.; Kubota, K.*; Ito, H.* Chem. Sci. 2019, 10, 8202–8210.
DOI: 10.1039/C9SC02185J

Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives

Akiyama, S.; Kubota, K.; Mikus, M. S.; Paioti, P. H. S.; Romiti, F.; Liu, Q.; Zhou, Y.; Hoveyda, A. H.*; Ito, H.* Angew. Chem. Int. Ed. 2019, 58, 11998–12003.
DOI: 10.1002/anie.201906283

Copper(I)-Catalyzed Enantioconvergent Borylation of Racemic Benzyl Chlorides Enabled by Quadrant-by-Quadrant Structure Modulation of Chiral Bisphosphine Ligands

Iwamoto, H.; Endo, K.; Ozawa, Y.; Watanabe, Y.; Kubota, K.; Imamoto, T.; Ito, H.* Angew. Chem. Int. Ed. 2019, 58, 11112–11117.
DOI: 10.1002/anie.201906011

Synthesis of 2-alkyl-2-boryl-substituted-tetrahydrofurans via copper(I)-catalysed borylative cyclization of aliphatic ketones

Kubota, K.; Uesugi, M.; Osaki, S.; Ito, H.* Org. Biomol. Chem. 2019, 17, 5680–5683.
DOI: 10.1039/C9OB00962K

Mechanochemistry allows carrying out sensitive organometallic reactions in air: Glove-box-and-Schlenk-line-free synthesis of oxidative addition complexes from aryl halides and palladium(0)

Kubota, K.*; Takahashi, R.; Ito, H.* Chem. Sci. 2019, 10, 5837–5842.
DOI: 10.1039/C9SC01711A

Luminescent mechanochromism of gold N-heterocyclic carbene complexes with hypso- and bathochromic spectral shifts

Seki, T.*; Kashiyama, K.; Ito, H.* Dalton Trans. 2019, 48, 7105–7109.
DOI: 10.1039/C9DT00566H

Concise Synthesis of Potassium Acyltrifluoroborates from Aldehydes by a Cu(I)-catalyzed Borylation/Oxidation Protocol

Taguchi, J.; Takeuchi, T.; Takahashi, R.; Masero, F.; Ito, H.* Angew. Chem. Int. Ed. 2019, 58, 7299–7303.
DOI: 10.1002/anie.201901748

Anisotropic strain release in a thermosalient crystal: Correlation between the microscopic orientation of molecular rearrangements and the macroscopic mechanical motion

Seki, T.*; Mashimo, T.; Ito, H.* Chem. Sci. 2019, 10, 4185–4191.
DOI: 10.1039/C8SC05563G

Dependence of Absorption and Emission Spectra on Polymorphs of Gold(I) Isocyanide Complexes: Theoretical Study with QM/MM Approach

Aono, S; Seki, T.; Ito, H.; Sakaki, S.* J. Phys. Chem. C 2019, 123, 4773–4794.
DOI: 10.1021/acs.jpcc.8b10602

Iridium(I)-Catalyzed C-H Borylation in Air by Using Mechanochemistry

Pang, Y.; Ishiyama, T.; Kubota, K.*; Ito, H.* Chem. Eur. J. 2019, 25, 4654–4659.
DOI: 10.1002/chem.201900685

Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry

Kubota, K.*; Seo, T.; Koide, K.; Hasegawa, Y.; Ito, H.* Nature Communications 2019, 10, 111.
DOI: 10.1038/s41467-018-08017-9

Soft Crystal Force Field for Reproducing the Crystal Structures of Aryl Gold Isocyanide Complexes

Nakayama, N.; Obata, S.; Hori, Y.; Goto, H.*; Seki, T.; Ito, H. J. Comput. Chem. Jpn. 2018, 17, 155–157.
DOI: 10.2477/jccj.2018-0031

A Gold Isocyanide Complex with a Pendant Carboxy Group: Orthogonal Molecular Arrangements and Hypsochromically Shifted Luminescent Mechanochromism

Seki, T.*; Kobayashi, K.; Mashimo, T.; Ito, H.* Chem. Commun. 2018, 54, 13160–13160.
DOI: 10.1039/C8CC06490C

Copper(I)-Catalysed Stereoselective Debromoborylation of Aliphatic 1,1-Dibromo-1-Alkenes with Bis(pinacolato)diboron

Pang, Y.; Kojima, R.; Ito, H.* Org. Biomol. Chem. 2018, 16, 6187–6190.
DOI: 10.1039/C8OB01778F

Copper(I)-Catalyzed Stereoselective Defluoroborylation of Aliphatic Gem-Difluoroalkenes

Ito, H.*; Seo, T.; Kojima, R.; Kubota, K. Chem. Lett. 2018, 47, 1330–1332.
DOI: 10.1246/cl.180656

Computational design of high-performance ligand for enantioselective Markovnikov hydroboration of aliphatic terminal alkenes

Iwamoto, H.; Imamoto, T.; Ito, H.* Nature Communications 2018, 9, 2290.
DOI: 10.1038/s41467-018-04693-9

A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-substituted Alkenes: Synthesis of Enantioenriched γ,γ-gem-Difluoroallylboronates

Kojima, R.; Akiyama, S.; Ito, H.* Angew. Chem. Int. Ed. 2018, 57, 7196–7199.
DOI: 10.1002/anie.201803663

Copper(I)-catalysed regio- and diastereoselective intramolecular alkylboration of terminal allenes via allylcopper(I) isomerization

Ozawa, Y.; Iwamoto, H.; Ito, H.* Chem. Commun. 2018, 54, 4991–4994.
DOI: 10.1039/C8CC02692K

meta-diisocyanide benzene-based aryl gold isocyanide complex exhibiting multiple solid-state molecular arrangements and luminescent mechanochromism

Seki, T.*; Ida, K.; Ito, H.* Mater. Chem. Front. 2018, 2, 1195–1200.
DOI: 10.1039/C8QM00074C

Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color

Jin, M.; Sumitani, T.; Sato, H.; Seki, T.*; Ito, H.* J. Am. Chem. Soc. 2018, 140, 2875–2879.
DOI: 10.1021/jacs.7b12455

Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-bis[tri-(p-fluorophenyl)phosphane-gold(I)-ethynyl]benzene

Jin, M.; Chung, T. J.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.* J. Am. Chem. Soc. 2017, 139, 18115–18121.
DOI: 10.1021/jacs.7b11316

Copper(I)-Catalyzed Diastereoselective Dearomative Carboborylation of Indoles

Hayama, K.; Kubota, K.; Iwamoto, H.; Ito, H.* Chem. Lett. 2017, 46, 1800–1802.
DOI: 10.1246/cl.170825

Copper(I)-Catalyzed Regio- and Stereoselective Intramolecular Alkylboration of Propargyl Ethers and Amines

Iwamoto, H.; Ozawa, Y.; Kubota, K.; Ito, H.* J. Org. Chem. 2017, 82, 10563–10573.
DOI: 10.1021/acs.joc.7b02071

Synthesis of Acylborons by Ozonolysis of Alkenylboronates: Preparation of an Enantioenriched Amino Acid Acylboronate

Taguchi, J.; Ikeda, T.; Takahashi, R.; Sasaki, I.; Ogasawara, Y.; Dairi, T.; Kato, N.; Yamamoto, Y.; Bode, J. W.; Ito, H.* Angew. Chem. Int. Ed. 2017, 56, 13847–13851.
DOI: 10.1002/anie.201707933

Stereodivergent Hydrodefluorination of gem-Difluoroalkenes: Selective Synthesis of (Z)- and (E)-Monofluoroalkenes

Kojima, R.; Kubota, K.; Ito, H.* Chem. Commun. 2017, 53, 10688–10691.
DOI: 10.1039/C7CC05225A

Tris(trimethylsilyl)silyl Boronate Esters: Novel Bulky, Air- and Moisture-Stable Silylboronate Ester Reagents for Boryl Substitution and Silaboration Reactions

Yamamoto, E.; Shishido, R.; Seki, T.; Ito, H.* Organometallics 2017, 36, 3019–3022.
DOI: 10.1021/acs.organomet.7b00476

Formal Nucleophilic Silyl Substitution of Aryl Halides with Silyllithium Reagents via Halogenophilic Attack of Silyl Nucleophiles

Yamamoto, E.; Ukigai, S.; Ito, H.* Synlett 2017, 28, 2460–2464.
DOI: 10.1055/s-0036-1590835

Tuning the Lifetime of Transient Phases of Mechanochromic Gold Isocyanide Complexes through Functionalization of the Terminal Moieties of Flexible Side Chains

Seki, T.*; Kashiyama, K.; Yagai, S.; Ito, H.* Chem. Lett. 2017, 46, 1415–1418.
DOI: 10.1246/cl.170482

Triboluminescence of Lanthanide Coordination Polymers with Face-to-Face Arranged Substituents

Hirai, Y.; Nakanishi, T. ; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Hasegawa, Y.* Angew. Chem. Int. Ed. 2017, 56, 7171–7175.
DOI: 10.1002/anie.201703638

Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups

Jin, M.; Seki, T.*; Ito, H.* J. Am. Chem. Soc. 2017, 139, 7452–7455.
DOI: 10.1021/jacs.7b04073

Low-Temperature-Selective Luminescent Mechanochromism of a Thienyl Gold Isocyanide Complex

Seki, T.*; Kobayashi, K.; Ito, H.* Chem. Commun. 2017, 53, 6700–6703.
DOI: 10.1039/C7CC03190D

Luminescent Mechanochromic 9-Anthryl Gold(I) Isocyanide Complex with an Emission Maximum at 900 nm after Mechanical Stimulation

Seki, T.*; Tokodai, N.; Omagari, S.; Nakanishi, T. ; Hasegawa, Y.; Iwasa, T.; Taketsugu, T.; Ito, H.* J. Am. Chem. Soc. 2017, 139, 6514–6517.
DOI: 10.1021/jacs.7b00587

Copper(I)-Catalyzed Stereo- and Chemoselective Borylative Radical Cyclization of Alkyl Halides Bearing an Alkene Moiety

Iwamoto, H.; Akiyama, S.; Hayama, K.; Ito, H.* Org. Lett. 2017, 19, 2614–2617.
DOI: 10.1021/acs.orglett.7b00940

Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Ketones: Synthesis of Enantioenriched Chiral Tertiary alpha-Hydroxyboronates

Kubota, K.; Osaki, S.; Jin, M.; Ito, H.* Angew. Chem. Int. Ed. 2017, 56, 6646–6650.
DOI: 10.1002/anie.201702826

Copper(I)-Catalyzed Boryl Substitution of Allyl Aminals: Selective Synthesis of Linear γ-Aminoallylboronates

Takenouchi, Y.; Ito, H.* Synthesis 2017, 49, 4738–4744.
DOI: 10.1055/s-0036-1588802

Transition-Metal-Free Boryl Substitution using Silylboranes and Alkoxy Bases

Yamamoto, E.; Maeda, S.; Taketsugu, T.; Ito, H.* Synlett 2017, 28, 1258–1267.
DOI: 10.1055/s-0036-1588772

Formal Nucleophilic Borylation and Borylative Cyclization of Organic Halides

Kubota, K.; Iwamoto, H.; Ito, H.* Org. Biomol. Chem. 2017, 15, 285–300.
DOI: 10.1039/C6OB02369J

Critical Role of Energy Transfer Between Terbium Ions for Suppression of Back Energy Transfer in Nonanuclear Terbium Clusters

Omagari, S. ; Nakanishi, T. ; Kitagawa, Y. ; Seki, T. ; Fushimi, K. ; Ito, H.; Meijerink, A. ; Hasegawa, Y. Sci. Rep. 2016, 6, 37008.
DOI: 10.1038/srep37008

Copper(I)-Catalyzed Enantioselective Boryl Substitution of Allyl Acylals: An Efficient Approach for Enantioenriched α-Chiral γ-Acetoxyallylboronates

Takenouchi, Y.; Kojima, R.; Momma, R.; Ito, H.* Synlett 2016, 28, 270–274.
DOI: 10.1055/s-0036-1588354

Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) Isocyanide Complex with Mechanical Reactivation

Seki, T.*; Jin, M.; Ito, H.* Inorg. Chem. 2016, 55, 12309–12320.
DOI: 10.1021/acs.inorgchem.6b02107

Luminescent Europium(III) Coordination Zippers Linked with Thiophene-Based Bridges

Hirai, Y.; Nakanishi, T.; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Hasegawa, Y. Angew. Chem., Int. Ed. 2016, 55, 12059–12062.
DOI: 10.1002/anie.201606371

Direct Introduction of a Dimesitylboryl Group Using Base-Mediated Substitution of Aryl Halides with Silyldimesitylborane

Yamamoto, E; Izumi, K.; Shishido, R.; Seki, T.; Tokodai, N.; Ito, H.* Chem. Eur. J. 2016, 22, 17547–17551.
DOI: 10.1002/chem.201604021

Synthesis of Enantiomerically Enriched Chiral Tetrahydroquinolines via Sequential Dearomatization/Enantioselective Borylation Reactions

Kubota, K.; Watanabe, Y.; Ito, H.* Adv. Synth. Catal. 2016, 358, 15, 2379–2384.
DOI: 10.1002/adsc.201600372

Luminescent mechanochromism of a chiral complex: Distinct crystal structure and color changes of racemic and homochiral gold(I) isocyanide complexes with a binaphthyl moiety

Jin, M.; Seki, T.*; Ito, H.* Chem. Commun. 2016, 52, 8083–8086.
DOI: 10.1039/C6CC03541H

Hyper-stable organo-EuIII luminophore under high temperature for photo-industrial application

Nakajima, A.; Nakanishi, T.; Kitagawa, Y.; Seki, T.; Ito, H.; Fushimi, K.; Hasegawa, Y. Sci. Rep. 2016, Article
DOI: 10.1038/srep24458

A Screening Approach for the Discovery of Mechanochromic Gold(I) Isocyanide Complexes with Crystal-to-Crystal Phase Transitions

Seki, T.*; Takamatsu, Y; Ito, H.* J. Am. Chem. Soc. 2016, 138, 6252–6260.
DOI: 10.1021/jacs.6b02409

Iridium(I)-catalyzed C−H Borylation of α,β-Unsaturated Esters with Bis(pinacolato)diboron

Sasaki, I.; Taguchi, J.; Doi, H.; Ito, H.*; Ishiyama, T.* Chem. Asian J. 2016, 11, 1400–1405.
DOI: 10.1002/asia.201600078

Computational Insight into the Enantioselective Nucleophilic Borylation of a Polarized C=O Double Bond Catalyzed by Di-phosphine-Borylcopper(I) Complexes

Kubota, K.; Jin, M.; Ito, H.* Organometallics 2016, 35, 1376–1383.
DOI: 10.1021/acs.organomet.5b00621

Enantioselective Synthesis of Chiral Piperidines via the Stepwise Dearomatization/Borylation of Pyridines

Kubota, K.; Watanabe, Y.; Hayama, K.; Ito, H.* J. Am. Chem. Soc. 2016, 138, 13, 4338–4341.
DOI: 10.1021/jacs.6b01375

Highly Selective Markovnikov Hydroboration of Alkyl-Substituted Terminal Alkenes with a Phosphine-Copper(I) Catalyst

Iwamoto, H.; Kubota, K.; Ito, H. Chem. Commun. 2016, 5916–5919.
DOI: 10.1039/C6CC00782A

Mechanical Path to a Photogenerated Structure: Ball Milling-Induced Phase Transition of a Gold(I) Complex

Sakurada, K.; Seki, T.; Ito, H. CrystEngComm 2016, 18, 7217–7220.
DOI: 10.1039/C5CE02565F

Regioselective C–H Borylation of Heteroaromatic Aldimines with Iridium Complexes

Sasaki, I.; Ikeda, T.; Amou, T.; Taguchi, J.; Ito, H.; Ishiyama, T. Synlett 2016, 27, 1582–1586.
DOI: 10.1055/s-0035-1561578

Detailed Investigation of the Structural, Thermal, and Electronic Properties of Gold Isocyanide Complexes with Mechano-Triggered Single

Seki, T.; Sakurada, K.; Muromoto, M.; Seki, S.; Ito, H. Chem. Eur. J. 2016, 22, 6, 1968–1978.
DOI: 10.1002/chem.201503721

Mechanochromic Luminescence Based on Crystal-to-Crystal Transformation Mediated by a Transient Amorphous

Yagai, S.; Seki, T.; Aonuma, H.; Kawabuchi, K.; Karatsu, T.; Okura, T.; Sakon, A.; Uekusa, H.; Ito, H. Chem. Mat. 2015, 28, 1, 234–241.
DOI: 10.1021/acs.chemmater.5b03932

Effective Photosensitized Energy Transfer of Nonanuclear Terbium Clusters Using Methyl Salicylate Derivatives

Omagari, S.; Nakanishi, T.; Seki, T.; Kitagawa, Y.; Takahata, Y.; Fushimi, K.; Ito, H.; Hasegawa, Y. J. Phys. Chem. A 2015, 119, 1943–1947.
DOI: 10.1021/jp512892f

Seven-Coordinate Luminophores: Brilliant Luminescence of Lanthanide Complexes with C3v Geometrical Structures

Yanagisawa, K.; Nakanishi, T.; Kitagawa, Y.; Seki, T.; Akama, T.; Kobayashi, M.; Taketsugu, T.; Ito, H.; Fushimi, K.; Hasegawa, Y. Eur. J. Inorg. Chem. 2015, 4769–4774.
DOI: 10.1002/ejic.201500820

Enhanced Electric Dipole Transition in Lanthanide Complex with Organometallic Ruthenocene Units

Hasegawa, Y.; Sato, N.; Hirai, Y.; Nakanishi, T.; Kitagawa, Y.; Kobayashi, A.; Kato, M.; Seki, T.; Ito, H.; Fushimi, K. J. Phys. Chem. A 2015, 119, 4825–4833.
DOI: 10.1021/acs.jpca.5b01809

Luminescent Coordination Glass: Remarkable Morphological Strategy for Assembled Eu(III) Complexes

Hirai, Y.; Nakanishi, T.; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Fueno, H.; Tanaka, K.; Sato, T.; Hasegawa, Y. Inorg. Chem. 2015, 54, 4364–4370.
DOI: 10.1021/acs.inorgchem.5b00145

Copper(I)-Catalyzed Diastereoselective Borylative Exo-Cyclization of Alkenyl Aryl Ketones

Yamamoto, E.; Kojima, R.; Kubota, K.; Ito, H. Synlett 2015, 27, 2, 272–276.
DOI: 10.1055/s-0035-1560721

Mismatched changes of the photoluminescence and crystalline structure of a mechanochromic gold(I) isocyanide complex

Seki, T.; Sakurada, K.; Ito, H. Chem. Comm. 2015, 51, 13933–13936.
DOI: 10.1039/C5CC04609B

Catalyst-Controlled Regiodivergent C-H Borylation of Multifunctionalized Heteroarenes by Using Iridium Complexes

Sasaki, I.; Taguchi, J.; Hiraki, S.; Ito, H.; Ishiyama, T. Chem. Eur. J. 2015, 21, 25, 9236–9241.
DOI: 10.1002/chem.201500658

Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis

Kubota, K.; Hayama, K.; Iwamoto, H.; Ito, H. Angew. Chem. Int. Ed. 2015, 54, 8809–8813.
DOI: 10.1002/anie.201502964

Copper(I)-Catalyzed Carbon–Halogen Bond-Selective Boryl Substitution of Alkyl Halides Bearing Terminal Alkene Moieties

Iwamoto, H.; Kubota, K.; Yamamoto, E; Ito, H. Chem. Comm. 2015, 51, 9655–9658.
DOI: 10.1039/C5CC02760H

Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies

Uematsu, R.; Yamamoto, E.; Maeda, S.; Ito, H.; Taketsugu, T. J. Am. Chem. Soc. 2015, 137, 4090–4099.
DOI: 10.1021/ja507675f

Boryl Substitution of Functionalized Aryl-, Heteroaryl- and Alkenyl Halides with Silylborane and an Alkoxy Base: Expanded Scope and Mechanistic Studies

Yamamoto, E.; Ukigai, S.; Ito, H. Chem. Sci. 2015, 6, 2943–2951.
DOI: 10.1039/C5SC00384A

Interconvertible Multiple Photoluminescence Color of a Gold(I) Isocyanide Complex in the Solid State: Solvent-Induced Blue-Shifted and Mechano-Responsive Red-Shifted Photoluminescence

Seki, T.; Ozaki, T.; Ohkura, T.; Asakura, K.; Sakon, A.; Uekusa, H.; Ito, H. Chem. Sci. 2015, 6, 2187–2195.
DOI: 10.1039/C4SC03960B

Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes

Kubota, K.; Iwamoto, H.; Yamamoto, E; Ito, H. Org. Lett. 2015, 17, 620–623.
DOI: 10.1021/ol503620n

Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes: An Efficient Route to Enantiomerically Enriched α-Alkoxyorganoboronate Esters

Kubota, K.; Yamamoto, E.; Ito, H. J. Am. Chem. Soc. 2015, 137, 1, 420–424.
DOI: 10.1021/ja511247z

Photoinduced Single-Crystal-to-Single-Crystal Phase Transition and Photosalient Effect of a Gold(I) Isocyanide Complex with Shortening Intermolecular Aurophilic Bonds

Seki, T.; Sakurada, K.; Muromoto, M.; Ito, H. Chem. Sci. 2015, 6, 1491–1497. Open Access Article.
DOI: 10.1039/C4SC02676D

A peptide ligase and the ribosome cooperate to synthesize the peptide ​pheganomycin.

Noike, M.; Matsui, T.; Ooya, K.; Sasaki, I.; Ohtaki, S.; Haman, Y.; Maruyama, C.; Ishikawa, J.; Satoh, Y.; Ito, H.; Morita, H.; Dairi, T. Nat. Chem. Biol. 2014, 11, 71–76.

Enhancement of Optical Faraday Effect of Nonanuclear Tb(III) Complexes

Nakanishi, T. ; Suzuki, Y. ; Doi, Y. ; Seki, T. ; Koizumi, H. ; Fushimi, K. ; Fujita, K. ; Hinatsu, Y. ; Ito, H. ; Tanaka, K. ; Hasegawa, Y. inorg. Chem. 2014, 53, 7635–7641.
DOI: 10.1021/ic5009363

Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-γ-Alkoxyallylboronates

Yamamoto, E.; Takenouchi, Y.; Ozaki, T.; Miya, T.; Ito, H. J. Am. Chem. Soc. 2014, 136, 47, 16515–16521.
DOI: 10.1021/ja506284w

Design amphiphilic dipolar π-systems for stimuli-responsive luminescent materials using metastable states

Yagai, S.; Okamura, S.; Nakano, Y.; Yamauchi, M.; Kishikawa, K.; Karatsu, T.; Kitamura, A.; Ueno, A.; Kuzuhara, D.; Yamada, H.; Seki, T.; Ito, H. Nature Communications 2014, 4013.
DOI: doi:10.1038/ncomms5013

Selective Synthesis of Organoboron Compounds with Copper(I)-Phosphine Complex Catalysts

Yamamoto, E.; Takenouchi, Y.; Kubota, K.; Ito, H. J. Synth. Org. Chem. Jpn. 2014, 72, 758–769.
DOI: 10.5059/yukigoseikyokaishi.72.758

Iridium-catalyzed ortho-C- borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

Sasaki, I.; Amou, T.; Ito, H.; Ishiyama, T. Org. Biomol. Chem. 2014, 12, 2041–2044.
DOI: 10.1039/C3OB42497A

Cholesterol-Aided Construction of Distinct Self-Organized Materials from Luminescent Gold(I)-Isocyanide Complex Exhibiting Mechanochromic Luminescence

K. Kawaguchi; T. Seki; T. Karatsu; A. Kitamura; H. Ito; S. Yagai Chem. Commun. 2013, 19, 11391–11394.
DOI: 10.1039/C3CC47162D

Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine-opper(I) Complex

Kubota, K.; Yamamoto, E.; Ito, H. Advanced Synthesis & Catalysis 2013, 355, 3527–3531.
DOI: 10.1002/adsc.201300765

Aromatic C- silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex

Ishiyama, T.; Saiki, T.; Kishida, E.; Sasaki, I.; Ito, H.; Miyaura, N. Org. Biomol. Chem. 2013, 11, 8162–8165.
DOI: 10.1039/C3OB41623B

Luminescence Color-Tuning through Polymorph Doping: Preparation of a White-Emitting Solid from a Single Gold(I)-socyanide Complex by Simple Precipitation

Seki, T.; Kurenuma, S.; Ito, H. Chem. Eur. J. 2013, 19, 16214–16220.
DOI: 10.1002/chem.201303394

Controlling Mechano- and Seeding-Triggered Single-Crystal-to-Single-Crystal Phase Transition: Molecular Domino with a Disconnection of Aurophilic Bonds

Seki, T.; Sakurada, K.; Ito, H. Angew. Chem., Int. Ed. 2013, 52, 12828–12832. VIP paper
DOI: 10.1002/anie.201307672

Effect of Ligand Polarization on Asymmetric Structural Formation for Strongly Luminescent Lanthanide Complexes

Y. Hasegawa; T. Ohkubo; T. Nakanishi; A. Kobayashi; M. Kato; T. Seki; H. Ito; K. Fushimi Eur. J. Inorg. Chem. 2013, 5911–5918.
DOI: 10.1002/ejic.201301102

Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

Sasaki, I.; Doi, H.; Hashimoto, T.; Kikuchi, T.; Ito, H.; Ishiyama, T. Chem. Commun. 2013, 49, 7546–7548.
DOI: 10.1039/C3CC44149K

Mechanical stimulation and solid seeding trigger single-crystal-to-single-crystal molecular domino transformations

Ito, H.; Muromoto, M.; Kurenuma, S.; Ishizaka, S.; Kitamura, N.; Sato, H.; Seki, T. Nature Communications 2013, 4, Article number:2009
DOI: 10.1038/ncomms3009

Copper(I)-Catalyzed Borylative Exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

Kubota, K.; Yamamoto, E.; Ito, H. J. Am. Chem. Soc. 2013, 135, 2635–2640.
DOI: 10.1021/ja3104582

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

Yamamoto, E.; Izumi, K.; Horita,Y.; Ito, H. J. Am. Chem. Soc. 2012, 134, 19997–20000.
DOI: 10.1021/ja309578k

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

Ito, H.; Horita, Y.; Yamamoto, E. Chem. Commun. 2012, 48, 8006–8008.
DOI: 10.1039/C2CC32778C

Practical procedure for copper(I)-catalyzed allylic boryl substitution with stoichiometric alkoxide base

Ito, H.; Miya, T.; Sawamura, M. Tetrahedron 2012, 68, 3423–3427.
DOI: 10.1016/j.tet.2011.08.081

Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides

Ito, H.; Kubota, K. Org. Lett. 2012, 14, 890–893.
DOI: 10.1021/ol203413w

Copper(I)-Catalyzed Allylic Substitution of Silyl Nucleophiles through Si-Si Bond Activation

Ito, H.; Horita, Y.; Sawamura, M. Advanced Synthesis & Catalysis 2012, 354, 813–817.
DOI: 10.1002/adsc.201100819

Mechanistic Insight into the Anomalous syn-Selectivity Observed during the Addition of Allenylboronates to Aromatic Aldehydes

Sasaki, Y.; Sawamura, M.; Ito, H. Chem. Lett. 2011, 40, 1044–1046.
DOI: 10.1246/cl.2011.1044

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

Sasaki, Y.; Horita, Y.; Zhong, C.; Sawamura, M.; Ito, H. Angew. Chem., Int. Ed. 2011, 50, 2778–2782.
DOI: 10.1002/anie.201007182

Enantioselective Synthesis of trans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative

Zhong, C.; Kunii, S.; Kosaka, Y.; Sawamura, M.; Ito, H. J. Am. Chem. Soc. 2010, 132, 11440–11442.
DOI: 10.1021/ja103783p

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates

Sasaki, Y.; Zhong, C.; Sawamura, M.; Ito, H. J. Am. Chem. Soc. 2010, 132, 1226–1227.
DOI: 10.1021/ja909640b

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

Ito, H.; Toyoda, T.; Sawamura, M. J. Am. Chem. Soc. 2010, 132, 5990–5992.
DOI: 10.1021/ja101793a

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

Ito, H.; Okura, T.; Matsuura, K.; Sawamura, M. Angew. Chem., Int. Ed. 2010, 122, 570–573.
DOI: 10.1002/ange.200905993

Direct Enantio-Convergent Transformation of Racemic Ssubstrates without Racemization or Symmetrization

Ito, H.; Kunii, S.; Sawamura, M. Nature Chemistry 2010, 2, 972–976.
DOI: 10.1038/nchem.801

The Synthesis of Allenes by Cu(I)-Catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes

Zhong, C.; Sasaki, Y.; Ito, H.; Sawamura, M. Chem. Commun. 2009, 5850–5852.
DOI: 10.1039/b910192f

Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex

Ito, H.; Saito, T.; Miyahara, T.; Zhong, C.; Sawamura, M. Organometallics 2009, 28, 4829–4840.
DOI: 10.1021/om900445w

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

Ito, H.; Sasaki, Y.; Sawamura, M. J. Am. Chem. Soc. 2008, 130, 15774–15775.
DOI: 10.1021/ja806602h

Reversible Mechanochromic Luminescence of [(C₆F₅Au)₂(μ-1,4-)]diisocyanobenzene

Ito, H.; Saito, T.; Oshima, N.; Kitamura, N.; Ishizaka, S.; Hinatsu, Y.; Wakeshima, M.; Kato, M.; Tsuge, K.; Sawamura, M. J. Am. Chem. Soc. 2008, 130, 10044–10045.
DOI: 10.1021/ja8019356

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

Ito, H.; Kosaka, Y.; Nonoyama, K.; Sasaki, Y.; Sawamura, M. Angew. Chem., Int. Ed. 2008, 47, 7424.
DOI: 10.1002/anie.200802342

Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Cu(I) Complexes with Wide Bite-Angle Chiral Bisphosphine Ligands: Optimization, Scope and Mechanistic Studies

Asano, Y.; Ito, H.; Hara, K.; Sawamura, M. Organometallics 2008, 27, 3901.
DOI: 10.1021/ol701534n

Synthesis and Sructural Characterization of a Tetranuclear Platinum(II) Metallamacrocycle Containing 1,3-Diisocyanoarene Ligands

Ito, H.; Maeda, T.; Sawamura, M. Bull. Chem. Soc. Jpn. 2007, 80, 1981.
DOI: 10.1246/bcsj.80.1981

Design and Synthesis of Isocyanide Ligands for Catalysis: Application to Rh-Catalyzed Hydrosilylation of Ketones

Ito, H.; Kato, T.; Sawamura, M. Chem. Asian J. 2007, 2, 1436.
DOI: 10.1002/asia.200700215

Copper-catalyzed Enantioselective Substitution of Allylic Carbonates with Diboron: An Efficient Route to Optically Active Chiral Allylboronates

Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M. J. Am. Chem. Soc. 2007, 129, 14856.
DOI: 10.1021/ja076634o

Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)-TRAP Complex

Asano, Y.; Hara, K.; Ito, H.; Sawamura, M. Org. Lett. 2007, 9, 3901–3904.
DOI: 10.1021/ol701534n

Electronically Tunable Compact Trialkylphosphines: SMAPs-bridged Bicyclic Phosphines

Ochida, A; Ito, S.; Miyahara, T.; Ito, H.; Sawamura, M. Chem. Lett. 2006, 35, 294–295.
DOI: 10.1246/cl.2006.294

Synthesis of New Bulky Isocyanide Ligands and their Use for Rh-catalyzed Hydrosilylation

Ito, H.; Kato, T.; Sawamura, M. Chem. Lett. 2006, 35, 1038–1039.
DOI: 10.1246/cl.2006.1038

Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)-phosphine Complex

Ito, H.; Watanabe, A.; Sawamura, M. Org. Lett. 2005, 7, 1869.
DOI: 10.1021/ol050559+

Gold(I)-phosphine Catalyst for the Highly Chemoselective Dehydrogenative Silylation of Alcohols

Ito, H.; Takagi, K.; Miyahara, T.; Sawamura, M. Org. Lett. 2005, 7, 3001.
DOI: 10.1021/ol050979z

Copper-catalyzed γ-Selective and Stereospecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds

Ito, H.; Kawakami, C.; Sawamura, M. J. Am. Chem. Soc. 2005, 127, 16034.
DOI: 10.1021/ja056099x

Nonvolatile Me₃P-like P-Donor Ligand: Synthesis and Properties of 4-Phenyl-1-phospha-4-silabicyclo-[2.2.2]-octane

Ochida, A.; Hara, K.; Ito, H.; Sawamura, M. Org. Lett. 2003, 5, 2671–2674.
DOI: 10.1021/ol0349099

Boration of an α, β-Enone Using a Diboron Promoted by a Copper(I)-Phosphine Mixture Catalyst

Ito, H.; Yamanaka, H.; Tateiwa, J.-i.; Hosomi, A. Tetrahedron Lett. 2000, 41, 6821–6825.
DOI: 10.1016/S0040-4039(00)01161-8

New Reactivity of a Reducing Reagent Generated from a Copper(I) Salt and a Hydrosilane: Selective Reduction of Ketones and Olefins Conjugated with an Aromatic Group

Ito, H.; Yamanaka, H.; Ishizuka, T.; Tateiwa, J.-i.; Hosomi, A. Synlett 2000, 479–482.
DOI: 10.1055/s-2000-6580

First Gold Complex-catalysed Selective Hydrosilylation of Organic Compounds

Ito, H.; Yajima, T.; Tateiwa, J.-i.; Hosomi, A. Chem. Commun. 2000, 981–982.
DOI: 10.1039/B001743O

An Unprecedented Catalytic Reaction Using Gold(I) Complexes

Ito, H.; Yajima, T.; Tateiwa, J.-i.; Hosomi, A. Tetrahedron Lett. 1999, 40, 7807–7810.
DOI: 10.1016/S0040-4039(99)01621-4

Highly Stereoselective Metathesis Reaction between Optically Active Hydrosilane and Copper(I) Salt in 1,3-Dimethyl-2-imidazolidinone

Ito, H.; Ishizuka, T.; Okumura, T.; Yamanaka, H.; Tateiwa, J.-i.; Sonoda, M.; Hosomi, A. J. Orgmet. Chem. 1999, 574, 102–106.
DOI: 10.1016/S0022-328X(98)00923-1

Palladium-catalyzed Coupling Reactions of N-Methoxy-N-methylcarbamoyl Chloride for the Synthesis of N-Methoxy-N-methylamides

Murakami, M.; Hoshino, Y.; Ito, H.; Ito, Y. Chem. Lett. 1998, 27, 163–164.
DOI: 10.1246/cl.1998.163

Uncatalyzed Aldol Reaction Using a Dimethylsilyl Enolate and α-Dimethylsilyl Ester in N,N-Dimethylformamide

Miura, K.; Sato, H.; Tamaki, K.; Ito, H.; Hosomi, A. Tetrahedron Lett. 1998, 39, 2585–2588.
DOI: 10.1016/S0040-4039(98)00275-5

Intramolecular Hydrogen Bond-promoted C-C Bond Formation: Reaction Rate Enhancement and Regioselective Allylation of Carbonyl Compounds

Ito, H.; Ujita, Y.; Tateiwa, J.-i.; Sonoda, M.; Hosomi, A. Chem. Commun. 1998, 2443–2444.
DOI: 10.1039/A807172A

New Method for Introduction of a Silyl Group into α,β-Enones using a Disilane Catalyzed by a Copper(I) Salt

Ito, H.; Ishizuka, T.; Tateiwa, J.-i.; Sonoda, M.; Hosomi, A. J. Am. Chem. Soc. 1998, 120, 11196–11197.
DOI: 10.1021/ja9822557

Selective O-Acylation of Silyl Enol Ethers with Acid Halides Mediated by a Copper(I) Salt

Ito, H.; Ishizuka, T.; Tateiwa, J.-i.; Hosomi, A. Tetrahedron Lett. 1998, 39, 6295–6298.
DOI: 10.1016/S0040-4039(98)01334-3

Di-functionalization of Alkenes Using an Oxidant Generated from Manganese(II) Chloride under Oxygen: Synthesis of γ-Lactones

Hojo, M.; Murakami, C.; Ohno, K.; Kuboyama, J.; Nakamura, S.-y.; Ito, H.; Hosomi, A. Heterocycles 1998, 47, 97.
DOI: 10.1002/chin.199821057

Highly Stereoselective Intramolecular Addition of a Hydroxyl Group to Vinylsilanes via 1,2-Silyl Migration

Miura, K.; Hondo, T.; Saito, H.; Ito, H.; Hosomi, A. J. Org. Chem. 1997, 62, 8292–8293.
DOI: 10.1021/jo971847p

New Access to Cross-coupling Reaction between Arylsilanes or Heteroarylsilanes and Aryl Halides Mediated by a Copper(I) Salt

Ito, H.; Sensui, H.-o.; Arimoto, K.; Miura, K.; Hosomi, A. Chem. Lett. 1997, 26, 639–640.
DOI: 10.1246/cl.1997.639

Generation of a Reducing Reagent from Copper(I) Salt and Hydrosilane. New Practical Method for Conjugate Reduction

Ito, H.; Ishizuka, T.; Arimoto, K.; Miura, K.; Hosomi, A. Tetrahedron Lett. 1997, 38, 8887–8890.
DOI: 10.1016/S0040-4039(97)10326-4

Direct Alkynyl Group Transfer from Silicon to Copper: New Preparation Method of Alkynylcopper (I) Reagents

Ito, H.; Arimoto, K.; Sensui, H.-o.; Hosomi, A. Tetrahedron Lett. 1997, 38, 3977–3980.
DOI: 10.1016/S0040-4039(97)00794-6

Manganese Ate Complexes as New Reducing Agents: Perfectly Regiocontrolled Generation and Reactions of the Manganese Enolates with Electrophiles

Hojo, M.; Harada, H.; Ito, H.; Hosomi, A. J. Am. Chem. Soc. 1997, 119, 5459–5460.
DOI: 10.1021/ja964054d

A New Type of Allyl- and Prop-2-ynyl-manganese Species: Generation and Reactions with Electrophiles

Hojo, M.; Harada, H.; Ito, H.; Hosomi, A. Chemical Communications 1997, 2077–2078.
DOI: 10.1039/A705771G

Preparation of (Alkaneimidoyl)lanthanides and Their Reactions with Carbonyl Compounds

Murakami, M.; Ito, H.; Ito, Y. Bulletin of the Chemical Society of Japan 1996, 69, 25–30.
DOI: 10.1246/bcsj.69.25

Alkyllithium-mediated Anomalous Trimerization of 2,6-Xylyl Isocyanide

Murakami, M.; Ito, H.; Ito, Y. Chem. Lett. 1996, 25, 7–8.
DOI: 10.1246/cl.1996.7

Regio- and Stereoselective Incorporation of a C-13 nuclide into D-ribo-Phytosphingosine via SmI2-mediated C-C Formation with C-13-Labeled Isocyanide

Murakami, M.; Ito, H.; Ito, Y. Chem. Lett. 1996, 25, 185–186.
DOI: 10.1246/cl.1996.185

Allylstannylation of Alkenes via Radical Process

Miura, K.; Matsuda, T.; Hondo, T.; Ito, H.; Hosomi, A. Synlett 1996, 555–556.
DOI: 10.1055/s-1996-5501

Allylstannylation of Alkynes via a Radical Process: Stereoselective Synthesis of Di- and Tri-substituted Vinylstannanes

Miura, K.; Itoh, D.; Hondo, T.; Saito, H.; Ito, H.; Hosomi, A. Tetrahedron Lett. 1996, 37, 8539–8542.
DOI: 10.1016/0040-4039(96)01986-7

Titanocene- and Zirconocene-mediated Cyclization of Allyl Propargyl Ethers. Stereoselective Synthesis of 3-Methylenetetrahydrofurans

Miura, K.; Funatsu, M.; Saito, H.; Ito, H.; Hosomi, A. Tetrahedron Lett. 1996, 37, 9059–9062.
DOI: 10.1016/S0040-4039(96)02128-4

”Tailor-made” Carbonyl Ylides: [3+2] Cycloaddition of the Parent and Optionally Substituted Nonstabilized Carbonyl Ylides

Hojo, M.; Aihara, H.; Ito, H.; Hosomi, A. Tetrahedron Lett. 1996, 37, 9241–9244.
DOI: 10.1016/S0040-4039(96)02194-6

Synthesis of Unsymmetrical α-Diketones via Autooxidation of α-Hydroxy Imines

Murakami, M.; Komoto, I.; Ito, H.; Ito, Y. Synlett 1993, 511–512.
DOI: 10.1055/s-1993-22511

Synthesis of α-Hydroxy Ketones by Samarium(II) Iodide-Mediated Coupling of Organic Halides, an Isocyanide, and Carbonyl-compounds

Murakami, M.; Kawano, T.; Ito, H.; Ito, Y. J. Org. Chem. 1993, 58, 1458–1465.
DOI: 10.1021/jo00058a028

Stereoselective Synthesis of 2-Amino Alcohols by Use of an Isocyanide as an Aminomethylene Equivalent

Murakami, M.; Ito, H.; Ito, Y. J. Org. Chem. 1993, 58, 6766.
DOI: 10.1002/chin.199412286